(2019) Atomic and Electronic Structure of a Heusler Alloy

Heusler compounds are promising materials for next generation devices for direct conversion of heat to electricity (thermoelectricity) and for magnetic computer memory. Performance in these applications depends sensitively on the arrangement of the atoms and the behavior of electrons, both of which are hard to predict and harder to control for Heuslers. We have grown thin films of FeVSb, a new Heusler compound, using molecular beam epitaxy, a kind of spray painting with “cans” of different atoms. The top picture is an electron microscope image showing the arrangement of the Fe, V, and Sb as different size dots. On the right, the image shows the material we want, FeVSb. On the left, there is a completely new, unexpected material, Fe2VSb, which is a new kind of magnet.

(2019) Reaching Underserved Audiences by Bringing Science to a Local Food Pantry

Not all members of our community have the time or resources to attend science outreach events. To reach some of those people, the Wisconsin MRSEC conducts its engaging, hands-on science activities to a local food pantry. Customers can wait up to 90 minutes at the food pantry, providing ample time for educational activities for kids, their parents, and other curious adult visitors. By bringing science and engineering activities to the food pantry, the Wisconsin MRSEC forms connections with and helps inspire a new, diverse audience composed entirely of economically disadvantaged members of the community.

(2019) All Aboard the Improv-Science Trolley: Learning Science in Unexpected Places

During the Wisconsin Science Festival, a statewide event that reaches over 30,000 people, the Wisconsin MRSEC developed an improvised science program held on a trolley that shuttled passengers between 27 science activities around Madison’s Capitol Square. On the trolley, an all-female team interviewed eight early career researchers about their research and lives to enable the ever-changing trolley audience to learn about the scientists and their science as well as ask their own questions of the researchers. More than 150 people rode the trolley and learned about scientific research during their journey. The event was an excellent professional development opportunity in science communication for the researchers and was covered by the Wisconsin State Journal.

(2019) New Precursors and Growth Processes for Complex Oxide Electronic Materials

Oxide compounds with multiple metal atoms are called complex oxides because they can have many chemical states, crystal structures, and a wide range of useful properties. Wisconsin MRSEC researchers have developed a new way to create crystals of an important series of oxides for quantum electronics, involving the lanthanide row of elements on the periodic table. The MRSEC team deposited lanthanide oxide films using a method called atomic layer deposition, using chemical precursors they developed. The resulting films are amorphous, with a disordered atomic structure, but heating them in contact with the surface of a substrate widely employed in oxide research transforms them into crystals templated by the substrate. This work required interdisciplinary collaboration among chemists, chemical engineers, and materials scientists, brought together by the MRSEC.

(2019) Nanoscale Control of Complex Oxide Crystallization

Small (nanometer-sized) crystals of multi-component, complex metal oxides have useful properties for applications in electronics, optics, sensors, and mechanical actuators. In order to realize this potential, engineers need to be able to put tiny crystals exactly where they are needed and to control the orientation of the crystal’s lattice. Researchers at the Wisconsin MRSEC and Argonne National Lab have studied a new way to place tiny oxide crystals through controlled, seeded crystallization of disordered, amorphous thin films. They have demonstrated controlled crystal growth at desired locations either from seeds of the same material (homoepitaxy) or seeds of a different material (heteroepitaxy). This work is an important step toward general control of oxide crystals and new applications.

(2019) Predicting Surface Diffusion from Molecular Structures

Many kinds of materials, including thin films, are created by adding atoms or molecules to a surface. As a result, understanding how molecules move along a surface is an important part of making new materials. In general, diffusion and crystal growth are much faster on the surface of glasses than in the interior. How much faster depends on how big the molecules are, and how many hydrogen bonds the surface molecule has to the bulk, as MRSEC researchers have recently discovered. This model works for many different molecules, giving a quick and easy way to predict surface motion and guide the synthesis of new materials.

(2019) Mechanical Properties of Structure-TunableVapor-Deposited TPD Glass

Creating glassy thin films of organic molecules at different temperatures changes both their stability in the glassy state – their density, and how hard they are to melt – and it changes how the molecules in the films are arranged – whether they tend to lie down flat on the surface or stand straight up. Wisconsin MRSEC researchers have shown that these changes in stability and average molecular orientation also change the mechanical properties of the film, including how stiff it is and how hard it is.

(2018) Seed: Synthetic soft matter created and inspired by communal behaviors of bacteria

This Seed project engaged underrepresented minority students in STEM through the MRSEC-sponsored summer REU program at UW-Madison. Doris A. Vargas Valentin, an undergraduate student from the University of Puerto Rico—Mayaguez, learned how to use dynamic light scattering and surface and surface tensiometry to characterize the self-assembly of smallmolecule amphiphiles in solution, analyze her experimental results, and present the results of her work in a formal setting during an eight-week stay in Madison. This experience also provided opportunities for Benjamin J. Ortiz, a senior graduate student who is also an underrepresented minority student in the Wisconsin MRSEC, to develop and hone his mentoring skills.

(2018) Seed: Synthetic soft matter created and inspired by communal behaviors of bacteria

Many bacteria have evolved dynamic networks of amphiphilic molecules that form a chemical "language" that they use to communicate and regulate group behaviors. This communication, in turn, governs the synthesis of bacterial biofilms and the production of other chemical goods, including other amphiphilic or redoxactive species, that are unique to large groups or communities of bacteria typically associated with bacterial infections. Researchers at the Wisconsin MRSEC are investigating the self-assembly of this chemical alphabet, and the properties of the nanostructures that form in solution and at interfaces, to design new types of synthetic and responsive soft materials that can respond to or “communicate” selectively with bacterial communities in ways that are distinct from those of existing materials, which are generally designed to interact with or kill individual bacterial cells.

(2018) Strain engineering of Heusler thin films and heterostructures

SEED-funded graduate students led scientific demonstrations for the general public during the 2018 Engineering Expo, hosted at the University of Wisconsin-Madison. The Kawasaki group also hosted a local middle school teacher as part of the Research Experiences for Teachers (RET) program of the Wisconsin MRSEC.